Journal of Applied Science and Engineering

Published by Tamkang University Press

1.30

Impact Factor

2.10

CiteScore

Ping Chang1 and Jeng-Shong Shih This email address is being protected from spambots. You need JavaScript enabled to view it.1

1Department of Chemistry National Taiwan Normal University Taipei, Taiwan 116, R.O.C.


 

Received: September 11, 2002
Accepted: October 11, 2002
Publication Date: December 1, 2002

Download Citation: ||https://doi.org/10.6180/jase.2002.5.4.02  


ABSTRACT


A multi-channel piezoelectric quartz crystal sensor with a homemade computer interface was prepared and employed in the present study to detect mixture of organic molecules. Back propagation neural network (BPN) was used to distinguish the species in the mixture organic molecules and multivariate linear regression analysis (MLR) was used to compute the concentration of the species. A six-channel piezoelectric sensor detecting organic molecules in static system was investigated and discussed. Amine, carboxylic acid, alcohol and aromatic molecules can easily be distinguished by this system with back propagation neural network. Furthermore, the concentrations of the organic compounds were computed with an error of about 10% by multivariate linear regression analysis (MLR). Detection of organic mixture with amine, carboxylic acid, alcohol and aromatic molecules by this method also had good qualitative and quantitative results. In order to achieve better distinguishability, change of fault-tolerance in back propagation neural network was also investigated and discussed in this study.


Keywords: Pizoelectric Crystal, Multichannel Sensor, Organic Vapours, Back Propagation Neural Network, Linear Regression Analysis


REFERENCES


  1. [1] Persaud, K.; Dodd, G. Nature 1982, 299, 352.
  2. [2] Carey, W. P.; Beebe, K. R.; Kowalski, B. R. Anal. Chem. 1986, 58, 149.
  3. [3] Sundgren, H.; Lundstrom, I.; Winquist, F. Sensors and Actuators B 1990, 2, 115.
  4. [4] Krebs, P.; Grisel, A. Sensors and Actuators B 1993, 13, 155.
  5. [5] Wang, X.; Yee, S.; Carey, P. Sensors and Actuators B 1993, 13-14, 458.
  6. [6] Lu, C. J.; Shih, J. S. Analytica Chimica Acta 1995, 306, 129.
  7. [7] Sheng, H. J.; Shih, J. S. Analytica Chimica Acta 1997, 350, 109.
  8. [8] Jane, Y. S.; Shih, J. S. Analyst 1995, 120, 517.
  9. [9] Chao, Y. C.; Shih, J. S. Analytica Chimica Acta 1998, 374, 39.
  10. [10] Chiou, C. S.; Shih, J. S. Analytica Chimica Acta 1998, 360, 69.
  11. [11] Chang, P.; Shih, J. S. Analytica Chimica Acta 1999, 380, 55.
  12. [12] Chang, P.; Shih, J. S. Analytica Chimica Acta 1998, 360, 61.
  13. [13] Sauerbrey, G. Z. Z. Phys. 1959, 155, 206.
  14. [14] Sauerbrey, G. Z. Z. Phys. 1964, 178, 457.
  15. [15] Chang, P.; Shih, J. S. Analytica Chimica Acta 2000, 403, 39.
  16. [16] Taylor, M.; Lisboa, P. Techniques and Application of Neural Networks 1993, Ellis Horwood.
  17. [17] Rumelhart, D. E.; McClelland, J. L. Parallel Distributed Processing; MIT Press, U.S.A. 1986.
  18. [18] ftp://ftp.sas.com/pub/neural/FAQ.html